Mesoporous carbon derived from vitamin B12: a high-performance bifunctional catalyst for imine formation.

نویسندگان

  • Bo Chen
  • Sensen Shang
  • Lianyue Wang
  • Yi Zhang
  • Shuang Gao
چکیده

Mesoporous carbon derived from natural vitamin B12 is applied for the first time in organic synthesis and exhibits exceptionally high dual activity for imine formation via the cross-coupling of alcohols with amines and the self-coupling of primary amines using molecular oxygen or air as the terminal oxidant.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Mesoporous metal-nitrogen-doped carbon electrocatalysts for highly efficient oxygen reduction reaction.

A family of mesoporous nonprecious metal (NPM) catalysts for oxygen reduction reaction (ORR) in acidic media, including cobalt-nitrogen-doped carbon (C-N-Co) and iron-nitrogen-doped carbon (C-N-Fe), was prepared from vitamin B12 (VB12) and the polyaniline-Fe (PANI-Fe) complex, respectively. Silica nanoparticles, ordered mesoporous silica SBA-15, and montmorillonite were used as templates for ac...

متن کامل

Bifunctional Mesoporous Carbon Nitride: Highly Efficient Enzyme-like Catalyst for One-pot Deacetalization-Knoevenagel Reaction

Recently, mesoporous carbon nitride (MCN) has aroused extensive interest for its potential applications in organocatalysis, photo- and electrochemistry and CO2 capture. However, further surface functionalization of MCN for advanced nanomaterials and catalysis still remains very challenging. Here we show that acidic carboxyl groups can be smoothly introduced onto the surface of well-ordered MCN ...

متن کامل

An Investigation into the Effect of Hydrotalcite Calcination Temperature on the Catalytic Performance of Mesoporous Ni-MgO-Al2O3 Catalyst in the Combined Steam and Dry Reforming of Methane

Several mesoporous nickel-based catalysts with MgO-Al2O3 as the catalyst support were prepared using a co-precipitation method at a constant pH. The supports were prepared from the decomposition of an Mg-Al hydrotalcite-like structure which had already been prepared with Mg/Al=1. Prior to impregnating 10 wt.% nickel on the supports, the precursor was decomposed at several ...

متن کامل

Investigation of the catalytic performance and coke formation of nanocrystalline Ni/SrO-Al2O3 catalyst in dry reforming of methane

In this study, nickel catalysts supported on mesoporous nanocrystalline gamma alumina promoted by various strontium contents were prepared by the impregnation method and employed in dry reforming of methane (DRM). The prepared catalysts were characterized using N2 adsorption (BET), temperature-programmed reduction and oxidation (TPR,) and oxidation (TPDTPO), X-ray diffraction (XRD), and scannin...

متن کامل

Carbon catalyst derived from Himalayan pine for the C-N coupling of organic molecules leading to pyrrole formation

Carbon catalyst consisting of a hybrid structure made up of amorphous carbon and nanographite was prepared from the leaves of Pinus Roxburghii. The catalyst was prepared through sodium hydroxide and hydrochloric acid treatment of the dried pine leaves; and further functionalized with sulfuric acid treatment to incorporate the acidic functionalities. The synthesized catalyst was characterized by...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 52 3  شماره 

صفحات  -

تاریخ انتشار 2016